The 54-year-old reality star wore a garish patent leather-sleeved trench coat and matching boots at The Drunken Monkey - a bar she's co-owned for nine years.
Puffing on a cigarillo, the buxom grandmother-of-two wore red lipstick on her notorious trout pout and her incredibly tanned skin was courtesy of Bottle Service bronzer.
'I had a lift and an implant, a tummy tuck. What else? Oh I just had my arms done. Laser lypo,' Raiola admitted on the January 28 episode of Bethenny.
Big Ang is the niece of Salvatore 'Sally Dogs' Lombardi - a deceased captain of the Genovese Crime Family.
The Miami Monkey star gushed over the party's Patron-infused chocolate-covered strawberries and meatballs from A Team caterer Ray Miles Jr.
This Sunday, Angela will make an appearance at Ed's Liquor Store in New Jersey to promote her gawdy wine line.
Not seen with Big Ang was her 25-year-old son Anthony 'AJ' D’Onofri and estranged husband, sanitation worker Neil Murphy.
However, the big-lipped ex-con did pose alongside Tough Love New Orleans star Elizabeth Vashisht wearing a tube mini-dress.
Raiola got help carrying the custom cake from Brooklyn bakery Isabella's Creations by her co-star Natalie Guercio. The Philadelphia brunette - who turns 32 this month - bared her midriff in a white crop-top alongside Jersey Shore alum Angelina Pivarnick.
Crimson-coiffed songstress Veronica Kole attended the premiere party in a silver halter dress featuring a furry collar and waist sash.
Not seen Wednesday were Big Ang's co-stars Drita D'Avanzo, Renee Graziano, and returning original castmember Karen Gravano.
The fifth season of Mob Wives will continue to air Wednesdays on VH1.
